水体系中含Mn~Ⅲ离子多酸化合物的原位合成、结构及性质研究

采用常规水溶液法在低热环境下得到了一种新的基于砷钨酸和Mn~Ⅲ的夹心型化合物,该化合物为单斜晶系,空间群为P2_1/c,晶胞参数为a=2.041 26(8)nm,b=3.227 58(8)nm,c=1.325 35(5)nm,β=94.427(3)°,V=8.705 8(5)nm~3,Z=4;分子式为(NH_4)_(10)[(MnH_2O)_2WO_2(AsW_9O_(33))_2]·3.5H_2O.性质分析表明,标题化合物对Hela细胞具有较高的抗肿瘤活性,可以作为潜在的抗肿瘤药物模型.     

Bi_2WO_6/Bi-TiO_2复合光催化剂的制备及催化氧化甲醛性能研究

研究采用水热法制备了花状Bi_2WO_6与TiO_2和Bi-TiO_2相复合的光催化剂,并使用新型LED节能灯为光源催化氧化室内甲醛.研究发现,粉末态Bi_2WO_6显示出花状结构,但无光催化氧化活性,而将Bi_2WO_6粉末与TiO_2和Bi-TiO_2复合后,两者相互作用所形成异质结结构形态,尤其Bi_2WO_6/Bi-TiO_2催化剂,所制样品展示出更佳的催化氧化活性,而经浸渍法所得样品几乎无光催化氧化活性,催化剂随着TiO_2和Bi-TiO_2含量的增加,复合催化剂显现出不尽相同的氧化活性规律,其中Bi_2WO_6与Bi-TiO_2质量比为1∶2样品表现最佳,36 h催化氧化甲醛转化率高达92.2%,甲醛浓度低于我国居室空气中甲醛最高容许浓度,且催化剂显示出良好的稳定性及重复性.     

微孔有机聚合物固相微萃取纤维的制备及在有机氯农药检测中的应用

利用1,3,6,8-四(4-醛基)芘和三聚氰胺为单体合成微孔有机聚合物(MOP),并将其固定在不锈钢丝上,制备成固相微萃取纤维涂层。将其用于顶空固相微萃取(HS-SPME),结合气相色谱-电子捕获检测手段,建立了对大米中有机氯农药的在线检测方法。实验考察了4种实验参数对富集能力的影响,得到了最优的实验条件:萃取温度80℃、萃取时间25 min、NaCl质量浓度200 g/L、解吸时间6 min。在此实验条件下,对有机氯农药的富集倍数达到115~318倍。方法在0.05~50μg/kg范围内具有良好的线性关系,检出限为2.4~11.3 ng/kg。同一纤维及不同纤维富集后测定结果的相对标准偏差范围分别为1.3%~13.1%和2.3%~13.6%。该方法简单、快速,可以实现对实际样品中有机氯农药的痕量分析。     

Effect of atomic oxygen irradiation on the structural and tribological characteristics of polytetrafluoroethylene and its composites

Based on the ground‐based simulation facility, the effects of atomic oxygen (AO) irradiation on the structural and tribological properties of pure polytetrafluoroethylene (PTFE) and carbon fiber and MoS₂‐filled PTFE composites were studied by scanning electron microscopy, X‐ray photoelectron spectroscopy, and a ball‐on‐disc tribometer. The results shown that AO irradiation had significant effects on the structural and tribological properties of pure PTFE, in which the surface morphologies, mass loss, friction coefficient, and wear rate had been changed greatly after AO irradiation. However, it was noticeable that the addition of carbon fiber and MoS₂ filler to PTFE could improve the AO resist capacity and tribological properties of PTFE composites significantly. Copyright © 2016 John Wiley & Sons, Ltd.     

Biomimetic superhydrophobic UHMWPE/nanosilica films with different sticky behavior on several metals

A kind of organic–inorganic composite film with biomimetic superhydrophobic performance was prepared on several metals including steel, aluminum, and copper. The organic matrix was ultrahigh‐molecular‐weight polyethylene (UHMWPE), and the inorganic filler was nanosilica. Scanning electron microscope observation indicated addition of nanosilica greatly changed the topography of the UHMWPE film. Special convexities were formed on the surfaces of the composite films, which made the composite films rougher than that of pure UHMWPE film. The nanosilica randomly scattered on the surface of the convexities and formed hierarchical structure similar to that of some plant leaves with superhydrophobic characteristics. Interestingly, it was found that there were remarkable differences between the sliding angles (SA) of water droplet on the composite films on different metals although the contact angles (CA) of water droplet on these films were quite close. The CA on the composite films on steel was about 157°, and the SA was larger than 90°, which demonstrated obvious superhydrophobic and sticky characteristic. But to the films on aluminum and copper, the CAs on them were larger than 160° and the SAs were between 3° and 4°, which meant excellent superhydrophobic and roll‐off performance. Scanning electron microscope observation indicated that there were some micro‐orifices in the film on steel and these micro‐orifices were connected to some extent. It was believed that these micro‐orifices provided capillary force and restrained sliding of water droplet. A sticky model based on capillary mechanism was proposed. Copyright © 2017 John Wiley & Sons, Ltd.     

Synthesis,Structures, and Luminescent Properties of Lanthanide Complexes with Triphenylphospine Oxide

Seven lanthanide complexes [Ln(OPPh₃)₃(NO₃)₃] ( 1 – 3 ) (OPPh₃ = triphenylphosphine oxide, Ln = Nd, Sm, Gd), [Dy(OPPh₃)₄(NO₃)₂](NO₃) ( 4 ), [Ln(OPPh₃)₃(NO₃)₃]₂ ( 5 – 7 ) (Ln = Pr, Eu, Gd) were synthesized by the reactions of different lanthanide salts and OPPh₃ ligand in the air. These complexes were characterized by single‐crystal X‐ray diffraction analysis, elemental analysis, IR and fluorescence spectra. Structure analysis shows that complexes 1 – 4 are mononuclear complexes formed by OPPh₃ ligands and nitrates. The asymmetric units of complexes 5 – 7 consist of two crystallographic‐separate molecules. Complex 1 is self‐assembled to construct a 2D layer‐structure of (4,4) net topology by hydrogen bond interactions. The other complexes show a 1D chain‐like structure that was assembled by OPPh₃ ligands and nitrate ions through C–H ··· O interactions. Solid emission spectra of compounds 4 and 6 are assigned to the characteristic fluorescence of Tb³⁺ (λ_em = 480, 574 nm) and Eu³⁺ (λ_em = 552, 593, 619, 668 nm).     

Fingerprint and multicomponent quantitative analysis for the quality evaluation of Sibiraea angustata leaves by HPLC-DAD and HPLC-ESI-MS/MS combined with chemometrics

Sibiraea angustata leaves, known as a traditional Tibetan medicine, have been specially used in the treatment of indigestion and obesity. In the study, a simple and sensitive high-performance liquid chromatography (HPLC) method with a diode array detector (DAD) was established to solve the problem of lacking quality standard of S. angustata leaves, including the fingerprint analysis and quantification of six characteristic components. The analytical method was validated for linearity, repeatability, stability, recovery, and specificity. Seventeen raw samples and 1 processed sample of S. angustata leaves were collected from different locations of China to establish the fingerprint. The chemometric methods, including similarity analysis (SA), principal component analysis (PCA), and hierarchical clustering analysis (HCA), were applied to distinguish the 18 batches of S. angustata samples. The results successfully sorted these samples into five clusters and kept in line with each other. According to the result of the fingerprint analysis, 21 peaks were extracted to be the common peaks and most of them were identified by mass spectrometry (MS) with electron-spray ionization (ESI) in the negative mode. Meanwhile, the loading plot of PCA further indicated that the peaks of neochlorogenic acid, chlorogenic acid, ferulic acid, rutin, hyperin, and isoquercitrin played a greater role in the discrimination among the 21 peaks. So the six components mentioned above were investigated as index constituents to evaluate the quality of S. angustata leaves from different locations. The study demonstrated that the developed new method was a beneficial approach for authentication and quality evaluation of S. angustata leaves.     

涉及极点重级与分担值的亚纯函数正规定则

运用分担值的思想证明了涉及极点重数的亚纯函数族的正规定则,所得结论推广了相关文献的主要结果.     

Effects of precursor concentration on the physicochemical properties of ambient-pressure-dried MTES based aerogels with using pure water as the only solvent

Journal of Sol-Gel Science and Technology - This work presents a facile synthesis approach of methyltriethoxysilane (MTES) based aerogels using pure water as the only solvent, and the effects of...     

树和单圈图的斜谱矩

给定图$G$,对图$G$的每条边确定一个方向,称为$G$的定向图$G^\sigma$, $G$称为$G^\sigma$的基础图. $G^\sigma$的斜邻接矩阵$S(G^\sigma)$是反对称矩阵,其特征值是0或纯虚数. $S(G^\sigma)$所有特征值的$k$次幂之和称为$G^\sigma$的$k$阶斜谱矩,其中$k$是非负整数.斜谱矩序列可用于对图进行排序.本文主要研究定向树和定向单圈图的斜谱矩,并对这两类图的斜谱矩序列依照字典序进行排序.首先确定了直径为$d$的树作为基础图的所有定向树中,斜谱矩序最大的$2\lfloor\frac{d}{4}\rfloor$个图; 然后确定以围长为$g$的单圈图作为基础图的所有定向单圈图中, 斜谱矩序最大的$2\lfloor\frac{g}{4}\rfloor+1$个图.